XFCE-Starzburg Theme
Full XFCE theme with XFWM theme.
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From the maker of Pewterburg-Gold, comes STARZBURG!
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Update 02-08-2010:
XFCE-Starzburg-Version 1.1

Created different coloring for the hover buttons and menu item buttons.
Middle screenshot shows the new colors of selected items.
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This is a customizable theme which allows you to select the panel style as well as the window manager styles.

The default style has stars in the dark panel, as well as stars in the window manager bar.

Do not like stars? No problem, it is easy to select a different panel style by editing the gtkrc file. Just read the Readme file for simple instructions.

The XFWM theme is also customizable, not only by the bar color styles, but also you can set your window manager like Mac OS with the window buttons set to the left of the window screen. Again, simple instructions are in the Readme file.

Screenshots:
Top: Default panel and window manager with stars.
Middle: Colored panel and window manager minus the stars.
Bottom: Flat black panel and window manager with buttons to the left.

The screenshots also show some of the icons from the Pewterburg-Icon theme:

http://www.xfce-look.org/content/show.php/Pewterburg-Color-Icons?content=118750
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Readme file:
Requires:
GTK 2.x
Pixmap Engine or Loaders
Murrine Engine (SVN version)
Pewterburg-Color icon theme (optional)

To install the Starzburg theme:

For system wide (All Users):
Copy XFCE-Starzburg folder into your themes directory (/usr/share/themes)

For single user (Only You):
Copy XFCE-Starzburg folder into your 'Hidden File' ~/.themes directory (/home/(username)/.themes)

Select XFCE-Starzburg from Settings > Appearance > Style
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The default theme includes the "star-filled" panels and window manager bar.
You can change the theme to have the panel colored without stars, or change to a flat black panel:

Open the gtkrc file with a text editor.
To change the panels to have NO stars with color or flat black, reverse the comment "#" tags.
(ie. #include "starpanel.rc" and include "colorpanel.rc" or "blackpanel.rc"

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There are two XFWM themes. XFWM-Starzburg-Nix has the window buttons in the right corner,
and the XFWM-Starzburg-Mac has the window buttons in the left corner.

To install the XFWM-Starzburg-Nix (or Mac) theme:

Open either the XFWM-Starzburg-Nix or XFWM-Starzburg-Mac folder.
There are three XFWM choices depending on the panel style selected in the XFCE theme.
You can copy the matching style or all of them.

For system wide (All Users):
Copy Starzburg-Black, Starzburg-Color or Starzburg-Starz (or all three) folder into your themes directory (/usr/share/themes)

For single user (Only You):
Copy Starzburg-Black, Starzburg-Color or Starzburg-Starz (or all three) folder into your 'Hidden File' ~/.themes directory (/home/(username)/.themes)

Select Starzburg-Black, Starzburg-Color or Starzburg-Starz from Settings > Window Manager > Style